pH

Irrigation water can be classified as acid, neutral, or alkaline. The degree of acidity or alkalinity of water can be described by a pH value. pH values range from 0 to 14; any value below 7.0 is considered acid, a value of 7.0 is neutral, and a pH above 7 is alkaline. Thus, water with a pH of 5.8 is acidic, whereas water with a pH of 7.9 is alkaline. Water with a pH in the range of 6.0 to 7.0 is most desirable for use on turfgrasses. Water with pH values outside of this range may not directly influence turfgrass performance, but indicates a need to evaluate other chemical components of the water.

Total alkalinity, bicarbonates and carbonates

Alkalinity is a measure of the acid-neutralizing capacity of water and has a desirable range of 80 to 100 mg/L. Bicarbonate (HCO3-) and carbonate (CO3-2), components of alkalinity, can influence soil properties and turfgrass performance. If bicarbonate and/or carbonate levels are high (>120 and 15 mg/L, respectively), these ions can react with calcium and magnesium in the soil to form insoluble calcium carbonate and magnesium carbonate (lime). This reaction reduces the amount of free calcium and magnesium in soil, allowing sodium to compete for and occupy negatively-charged exchange sites on clay particles. Excess sodium in clay results in destruction of soil structure and reduced water percolation though the soil profile. This effect is referred to as the sodium permeability hazard and is assessed by calculating a residual sodium carbonate value.

Residual Sodium Carbonate (RSC)

The sodium permeability hazard for irrigation water is usually assessed when bicarbonate and carbonate levels are >120 and 15 mg/L, respectively. Residual sodium carbonate (RSC) is a common means of assessing the sodium permeability hazard, and takes into account the bicarbonate/carbonate and calcium/magnesium concentrations in irrigation water. RSC is important because it's not the absolute bicarbonate and carbonate concentrations that are important, but instead, the relative concentrations of bicarbonate and carbonate compared to concentrations of calcium, magnesium, and sodium.

RSC is calculated as follows:

RSC (meq/L) = (HCO3- + CO3-2) – (Ca + Mg)

Note that for this equation, all concentrations are expressed in meq/L. Typically, water with a RSC value of 1.25 meq/L or lower is safe for irrigating turf. Water with a RSC value between 1.25 and 2.5 meq/L is marginal, and above 2.5 meq/L is considered to be of poor quality.

Hardness

Hardness is determined by the calcium and magnesium content of water. Moderate levels are beneficial because they inhibit plumbing system corrosion. However, when too high, calcium and magnesium build up on contact surfaces, plug pipes and damage water heaters. Removal of hardness by using a water softener is necessary only if the water is causing problems. Use of water softeners may result in undesirable levels of sodium in drinking water and may increase system corrosion. A water hardness of about 100 mg/L provides excellent corrosion control and is usually aesthetically acceptable.

Electrical conductivity (EC) and total dissolved solids (TDS)

EC is a measure of the degree in which water conducts electricity. It is determined by passing an electrical current through a water sample and recording the resistance in mmhos/cm or dS/m. EC is used to estimate the concentration of TDS in water, using the following equation:

TDS (mg/L) = EC (mmhos/cm) x 640

TDS is occasionally referred to as total dissolved salts (also abbreviated TDS) or total soluble salts (TSS), and both are determined using the same equation.

Acceptable TDS concentrations for turfgrass irrigation range from 200 to 500 mg/L (EC = 0.31 to 0.78 mmhos/cm). TDS concentrations higher than 2,000 mg/L (EC = 3.1 mmhos/cm) can damage turfgrasses. If using irrigation water with a TDS concentration higher than 500 mg/L, attention should focus on irrigation duration and frequency, drainage, and turfgrass species selection.

Sodium

Sodium exists in nearly all irrigation water and is not necessarily a cause for concern unless high concentrations are present. High concentrations (> 70 mg/L) can be detrimental to both turf and soils. Sodium in irrigation water can be absorbed by roots and foliage, and foliar burning can occur if sufficient amounts accumulate in leaf tissue. Grasses grown on golf course putting greens (creeping bentgrass and annual bluegrass)

Sodium adsorption ratio (SAR)

The relative concentrations of sodium, calcium, and magnesium are important determinants of irrigation water quality. Calcium and magnesium play a major role in maintaining structure of clay-containing soils. If water with excess sodium and low calcium and magnesium is applied frequently to clay soils, the sodium will tend to displace calcium and magnesium on clay particles, resulting in breakdown of structure, precipitation of organic matter, and reduced permeability.

SAR is used to assess the relative concentrations of sodium, calcium, and magnesium in irrigation water and provide a useful indicator of its potential damaging effects on soil structure and permeability.

Typically a SAR value below 3.0 is considered very safe for turfgrasses. Over time, water with a SAR of 9.0 or above can cause significant structural damage to clay soils. Sandy soils are not as susceptible to structure and permeability problems, and can tolerate higher SAR values (up to 10 in most cases).

Chloride

Chloride contributes to salinity of irrigation water, and when concentrations are high enough, can be toxic to plants. Turfgrasses are not particularly sensitive to chloride, and can tolerate levels up to 100 mg/L. Turfgrasses can sustain injury when irrigated with water containing >355 are particularly susceptible to sodium toxicity because they are mowed very short, irrigated frequently, and subjected to other stresses. mg/L of chloride. Turfgrass managers should be aware that some ornamental plants are sensitive to chloride concentrations above 70 mg/L.

Boron

Boron is essential for plant growth at very low concentrations. However, it can be quite toxic to some ornamental plants at concentrations as low as 1 to 2 mg/L in irrigation water; with symptoms appearing as necrosis on margins of older leaves. By comparison, turfgrasses are more tolerant of boron, and are capable of growing in soils with boron concentrations of 10 mg/Kg. To be safe, it is best to use irrigation water with boron concentrations < 2 mg/L for turfgrasses.

Nutrients in irrigation water

Irrigation water contains plant nutrients in varying concentrations. Depending on concentrations, nutrients can influence fertility programs and have an environmental impact on ground and surface water. Nitrogen has a significant influence on plant growth, and may present a hazard for drinking water sources if nitrate levels are 10 mg/L or more. Phosphorus concentrations should be as low as possible (lower than 1.0 mg/L) to avoid causing algal blooms in holding ponds and phosphorus loading in surface streams and lakes. Guidelines for nutrient concentrations are provided in Table 1.

Table 1. Guidelines for nutrient concentrations in irrigation water (mg/L)¹.
¹Guidelines based on the suggestions of Duncan, R.R., R.N. Carrow, and M. Huck. 2000. Understanding Water Quality and Guidelines to Management. USGA Green Section Record. September-October, pp. 14-24.
Macronutrient Low Normal High Very High
Nitrate (NO3-) < 5 5-50 50-100 > 100
Ammonium (NH4+) > 2 2-75 75-100 > 100
Phosphorus (P) < 0.01 0.1-0.4 0.4-0.8 > 0.8
Potassium (K) < 5 5-20 20-30 > 30
Calcium (Ca) < 20 20-60 60-80 > 80
Magnesium (Mg) < 10 10-25 25-35 > 35
Sulfur < 10 10-30 30-60 > 60
Micronutrient Acceptable Range Suggested maximum concentration
Iron (Fe) 2.4-4.0 5.0
Manganese (Mn) < 0.2 0.2
Copper (Cu) < 0.2 0.2
Molybdenum (Mo) < 0.1 0.1
Zinc < 0.3 2.0
Boron < 2.0 2.0

Ag Analytical Services Lab

Address

720 Tower Rd
University Park, PA 16802
Directions

Hours: Monday-Friday, 8:00 AM - 4:00 PM

Ag Analytical Services Lab

Address

720 Tower Rd
University Park, PA 16802
Directions

Hours: Monday-Friday, 8:00 AM - 4:00 PM